Journal of Liaoning Petrochemical University
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Preparation and Diesel Oil Dehydrocracking Activity of  Large Pore Ni2P/γ-A12O3 Catalyst
XUAN Li-wei,WANG Huan,ZHANG Ji-qing,WANG Hai-yan, MENG Xiu-hong
Abstract384)      PDF (298KB)(316)      
Using large pore γ-Al2O3 prepared by acid precipitation, the Ni2P(25%)/γ-Al2O3 catalyst was prepared as the support by the impregnation method. The test results of XRD, BET and mercury porosimetry show that the large pore γ-Al2O3 has preferable surface area and pore structure. After in-situ reduction,the effects of preparation conditions and reaction conditions on dehydrocracking activity of the catalyst were studied in a fixed-bed down-flow reactor with the diesel as the material. The results show that desulfurization degree of 98.2% would be attained under the optimum condition as follows: synthesis temperature of 80 ℃, pH of 8,reaction temperature of 360 ℃,reaction pressure of 4.0 MPa,liquid hourly space velocity of 1.0 h-1 and volume ratio of hydrogen to cyclohexane of 500∶1.
2012, 32 (3): 25-28.
Preparation and Property on Cyclohexane  Dehydrogenation Activity of Mo2C/CCA
LIU Zhao, MA Jun, WANG Hai-yan,BAI Ying-zhi, LIU Lu
Abstract297)      PDF (281KB)(348)      
The Mo3O/CCA was prepared by impregnation method using the (NH4)6Mo7O24·4H2O as the molybdenum source, carbon covered γ-Al2O3 (CCA) as support, and n-hexane as the carbon source. After carbonization of Mo3O/CCA obtained Mo2C/CCA. The catalysts prepared at different carbonization temperature were characterized by XRD. The effects of preparation and reaction conditions on dehydrogenation activity of the catalyst were studied in a fixed-bed down-flow reactor. The results show that the conversion of cyclohexane up to 91% was attained under the optimum condition as follows: CCA carbon covered 7.82%, final carbonization temperature 650 ℃, reaction temperature 475 ℃, reaction pressure 0.1 MPa, liquid hourly space velocity 2 h-1 and volume ratio of hydrogen to cyclohexane 200∶1.
2012, 32 (3): 13-16.
 
Econometric Analysis of Repercussion of Chinese Petroleum Industry
ZHOU Chang-mao,WANG Hai-yan
Abstract423)      PDF (156KB)(442)      
   
Industry repercussion effect is not only one of the foundations to measure the position of one industry in national economy system, but also a main basis for government to locate a leading industry. Through introducing the sensitivity degree coefficient and influencing power coefficient, the repercussion of Chinese petroleum industry has been measured. Furthermore, the strategic position of it in national economy was researched with econometric measures. The strategic attribute of petroleum industry was proved based on the studies above.
2011, 31 (3): 84-88. DOI: 10.3696/j.issn.1672-6952.2011.03.023
The Preparation of Hydrodenitrogenation Activity of the MoP/TiO 2-SiO 2-Al 2O 3
JIANG Xu,GU Yong-he,WANG Hai-yan*,WEI Min,BAI Ying-zhi,MA Jun
Abstract371)      PDF (260KB)(265)      
 
The TiO 2-SiO 2-Al 2O 3 composite support was prepared by sol-gel method, and then the MoP/TiO 2-SiO 2-Al 2O 3 catalyst was prepared in the way of co-impregnation. XRD results show that the diffraction peaks of TiO 2 crystalline phase is due to anatase and SiO 2 is mostly amorphous dispersed in γ-Al 2O 3 cystal surface. After in-situ reduction, the hydrodearomatization (HDA) activity of the catalyst was investigated in the fixed bed reactor. The results suggest that the mole ratio of Ti, Si and Al have a great influence on the activity of composite support catalyst. HDA activity of the MoP/TiO 2-SiO 2-Al 2O 3 catalyst shows the highest activity (65.6%) when the ratio of n(Ti)∶n(Si)∶n(Al) was 1∶1∶4, the Mo loading amount is 20%. In addition, the results also show that the HDA rate of the catalyst with the composite TiO 2-SiO 2-Al 2O 3 support was 19.6% and 13.6% higher than the traditional cataslysts of γ-Al 2O 3 and SiO 2-Al 2O 3, respectively.
2010, 30 (3): 24-27. DOI: 10.3696/j.issn.1672-6952.2010.03.007